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I'd probably go for:

Alpha Flight Special: First Flight - While it deals with a team we never see again I think this issue does well to capture Mac's attitude ad his leadership issues, springing...

Yeah, but I'd say not all history matters straight off the bat. I'm trying to pick out key issues that would pique a new readers interest and then make them want to delve further into AF-lore.
And...

That's an awful lot for a newbie to throw themselves straight into!

Okay, I'll make it 5 storyarcs/individual issues instead.

So, with the launch of Volume 4 and a lot of new readers it's always good to be able to point them in the direction of more Alpha Flight goodness.

Let's take Uncanny #109, 120-121, 139-140,...